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Ligand steric effects on naphthyl-α-diimine nickel catalyzed α-olefin polymerization

Published in Chinese Journal of Polymer Science

Naphthyl-a-diimine nickel complexes with systematically varied ligand sterics, activated by modified methylaluminoxane (MMAO), were tested in the polymerization of higher a-olefin (1-hexene, 1-decene and 1-hexadecene) under suitable conditions. The polymerization results indicated the possibility of precise microstructure control, depending on cata...