Using density functional theory we perform theoretical investigations of the electronic properties of a freestanding one-dimensional organometallic vanadium-benzene wire. This system represents the limiting case of multidecker V-n(C6H6)(n+1) clusters which can be synthesized with established methods. We predict that the ground state of the wire is ...
Using density functional theory we perform theoretical investigations of the electronic properties of a freestanding one-dimensional organometallic vanadium-benzene wire. This system represents the limiting case of multidecker V-n(C6H6)(n+1) clusters which can be synthesized with established methods. We predict that the ground state of the wire is ...
The use of N-heterocyclic carbene (NHC) as a ligand in the gold(I)-catalyzed cycloisomerization of enyne results in the assembly of a new carbocyclic product.
A number of cationic gold(I) complexes have been synthesized and found to be stabilized by the use of N-heterocyclic carbene ligands. These species are often employed as in situ-generated reactive intermediates in gold catalyzed organic transformations. An isolated, well-defined species was tested in gold-mediated carbene transfer reactions from et...
X / 1 / 1 / 27 / 25 / scie / scopus
Using density functional theory we perform theoretical investigations of the electronic properties of a freestanding one-dimensional organometallic vanadium-benzene wire. This system represents the limiting case of multidecker V-n(C6H6)(n+1) clusters which can be synthesized with established methods. We predict that the ground state of the wire is ...
A numerical method for multiphase incompressible thermal flows with solid-liquid and liquid-vapor phase transformations is presented. The flow is mainly driven by thermocapillary force and vaporization. Based on the level set method and mixture continuum model, a set of governing equations valid for solid, liquid, and vapor phases is derived, consi...
A new aluminum hydroxide-supported palladium catalyst (1) made by a one-pot synthesis through nanoparticle generation and gelation shows a dual catalytic activity for olefinic hydrogenation and aerobic alcohol oxidation. / X / 1 / 1 / 158 / 15 / scie / scopus
This paper presents a distortion-tolerant 3-D volume object recognition technique. Volumetric information on 3-D objects is reconstructed by x-ray imaging. We introduce 3-D feature extraction, volume matching, and statistical significance testing for the 3-D object recognition. The 3D Gabor-based wavelets extract salient features from 3-D volume ob...
This paper presents a distortion-tolerant 3-D volume object recognition technique. Volumetric information on 3-D objects is reconstructed by x-ray imaging. We introduce 3-D feature extraction, volume matching, and statistical significance testing for the 3-D object recognition. The 3D Gabor-based wavelets extract salient features from 3-D volume ob...
