MIKHAILOV, OLEG V CHACHKOV, DENIS V
Published in
Journal of Chemical Sciences
Using the density functional theory (DFT) in the OPBE/TZVP//QZP level, the geometric parameters and total energies of the molecular structures of macrotricyclic complexes of 3d and 4d elements with the so-called open contour, which can arise during template synthesis between M(II) of the indicated elements, dithiooxamide H2N–C(=S)–C(=S)–NH2 and gly...
PARMAR, K K PADMAVATHI, G SHARMA, SUMEET KUMAR JASRA, RAKSHVIR
Published in
Journal of Chemical Sciences
Sulfur compounds are widely used as additives in commercial cracking processes as they play an important role in coke inhibition, CO formation and light olefins yield. It is important to understand the thermal decomposition of sulfur additives and their impact on coke formation to enable the effective utilization of the additives. Thermal decomposi...
Mukherjee, Saumyak Mondal, Sayantan Bagchi, Biman
Published in
Journal of Chemical Sciences
Many known and unknown factors play significant roles in the persistence of an infectious disease, but two that are often ignored in theoretical modelling are the distributions of (i) inherent susceptibility (σinh\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \u...
Koshti(S), Vijay S Chandanshive, Amol C Mote, Nilesh R Chikkali, Samir H
Published in
Journal of Chemical Sciences
As phosphines readily invert, the synthesis of P-chiral phosphines is a challenging task and has been rarely investigated. We report the synthesis of a nickel complex [Ni-((S,S)Me-FerroLANE)(phenyl)(I)] (Ni-Cat.1) and its performance in a P-C coupling reaction to generate P-chiral phosphine. The Ni-Cat.1 was synthesized by mixing ligand (S,S) Me-Fe...
Prasad, Bhagavatula L V Sivasankaran, Prathap Chandran Patel, Pitambar Malekar, Pushpa V Maya, K V Ramana, Chepuri V
Published in
Journal of Chemical Sciences
Klovak, Viktoriia Kulichenko, Sergey Lelyushok, Serhii
Published in
Journal of Chemical Sciences
The influence of cationic, anionic, and nonionic surfactant solutions on the nature of the fluorescence spectra of reagents of different charges and hydrophobicity in aqueous solutions has been studied. The increase in the surfactant analytical signal with increasing contribution of the role of electrostatic interactions between the reagent particl...
Ahmadi, Samaneh Azizian, Javad
Published in
Journal of Chemical Sciences
In the present work (E) -2-(4-oxo-4,5-dihydrothiazol-2-yl)-2-(2-oxoindolin-3-ylidene) acetonitrile compounds were obtained from the reaction of isatin and 2-(4-oxo-4,5-dihydrothiazol-2-yl) acetonitrile in a green solvent with good yield. In this paper, we have developed an attractive alternative to the classical Knovnagel condensation for the Diast...
Choe, Donghwan Kim, Cheal
Published in
Journal of Chemical Sciences
A novel carbazate-based fluorescent sensor BC-MS was developed for the detection of Zn2+. In the presence of Zn2+, BC-MS showed a strong fluorescence enhancement with a 1:1 stoichiometry. Significantly, BC-MS could determine the presence of Zn2+ without the inhibition of Cd2+. The detection mechanism of BC-MS toward Zn2+ was proposed through analyt...
Tuwar, Suresh M Hanabaratti, Rohini M
Published in
Journal of Chemical Sciences
AbstractKinetics of Permanganate (MnO4−) oxidation of antiviral drug, valacyclovir hydrochloride (VCH) has been studied spectrophotometrically at a constant ionic strength of 0.1 mol dm−3. The reaction exhibiting a 2:1 stoichiometry (MnO4−:VCH) has been studied over a wide range of experimental conditions. It was found that the rate enhancement was...
Chandrasekhar, T K Giribabu, L Sastri, Chivukula V
Published in
Journal of Chemical Sciences
