Published in Chemical Papers
Particle horizontal transport and vertical entrainment of widely different materials (silica sand, alumina, ceramsite, dry sludge, and wood shreds) are explored by experimental measurements. Experiments have been performed with two very narrow fractions of solids (0.315–0.50 mm and 1.4–1.6 mm) on a laboratory setup. Simple empirical correlations ar...
Published in Chemical Papers
Medroxyprogesterone acetate (MPA), relative molecular mass is only 344.5 and it has no immunogenecity. The methods of the carbodiimides and the mixed anhydride were both adopted to couple MPA with bovine serum albumin, the carrier protein. The coupling rates of conjugate using the above methods were estimated to be 14 and 20 by ultraviolet spectrop...
Published in Chemical Papers
A new volumetric method for monitoring the oscillating Belousov—Zhabotinsky reaction with oxalic acid is described. While an oscillatory behavior in the potential of the Pt redox electrode at slow stirring without inert gas bubbling can be observed, a monotonous, nonoscillatory course was found both at the slow and rapid stirring rates for the carb...
Published in Chemical Papers
Synthesis of N-and C-substituted derivatives of benzo[h][1,6]naphthyridine, bearing 2-hydroxyethyl group has been made by quaternization reaction and by condensation of corresponding methylbenzonaphthyridines with formaldehyde. For six derivatives of isomeric benzo[c][1,5]-, benzo[h][1,6]-, and benzo[f][1,7]naphthyridines the 13C NMR spectra are di...
Published in Chemical Papers
Nine potential AChE reactivators were synthesized using modification of currently known synthetic pathways. Their potency to reactivate AChE inhibited by cyclosarin nerve agent was tested in vitro. According to the previous results, 1,4-bis(2-hydroxyiminomethylpyridinium)butane dibromide seems to be the most potent AChE reactivator. The reactivatio...
Published in Chemical Papers
Heterogeneous extracellular polysaccharide galactoxylomannan has been isolated from the culture medium of the acapsulated mutant Cryptococcus laurentii 17-3-6 as the main extracellular polysaccharide (90%). Size-exclusion chromatography of precipitated polysaccharides afforded two molecular fractions with molecular mass 75 kDa and 20 kDa. Mannose, ...
Published in Chemical Papers
A reliable procedure for the electrothermal atomic absorption spectrometry (ETAAS) determination of gold and silver in waters at trace level is described. The method is based on prior separation and preconcentration of the metals using a chelating sorbent SPHERON® Thiol 1000 after acidification of water samples (pH
Published in Chemical Papers
The aminothiadiazole (II) on treatment with aromatic aldehydes yielded Schiff bases, which cyclized to thiazolidinone derivatives by reaction with thioglycolic acid. Reaction of II with phenyl isocyanate and phenyl isothiocyanate afforded the carbamide and carbothiamide derivatives, respectively, which on reaction with malonic acid in acetyl chlori...
Published in Chemical Papers
Efficiency of the suggested tandem technique of Marinković burner was studied in terms of the influence of the PC-controlled DC arc of the different intensities (10 A, 15 A, 20 A, 25 A) on the evaporation process. Higher intensities than 25 A did not allow to use the given experimental equipment since they cause plasma instability and periodic plas...
Published in Chemical Papers
The effects of the complexes of the type M(L)2(nia)2 (M = Cd or Zn; L = acetate (ac) or NCS−; nia = nicotinamida) on reduction of chlorophyll content in suspensions of Chlorella vulgaris and inhibition of photosynthetic electron transport in spinach chloroplasts were investigated. The inhibitory effects of the studied compounds depended on the cent...
