Published in Chemical Communications
Rhodium(iii)-catalyzed mild benzylic α-fluoroalkenylation of 8-methylquinolines with gem-difluorostyrenes has been developed. This reaction occurred via C-H activation and C-F cleavage and is applicable to a wide range of substrates, leading to the synthesis of Z-alkenyl fluorides under mild and redox-neutral conditions with high regio- and stereos...
Published in Chemical Communications
An efficient and redox-neutral naphthol synthesis has been realized via rhodium(iii) catalyzed C-H activation of α-carbonyl nitrones and annulation with alkynes, where the nitrone group functioned as a traceless directing group.
Published in Chemical Communications
Phosphorene, or two-dimensional (2D) black phosphorus (BP) was the first synthetic 2D elemental allotrope beyond graphene to be isolated and studied. It is useful due to its high p-type carrier mobility and direct band gap that is tunable in the range ca. 0.3-2 eV thus bridging the energy gap between graphene and transition metal dichalcogenides su...
Published in Chemical Communications
Published in Chemical Communications
Published in Chemical Communications
Published in Chem Commun (Camb)
Published in Chemical Communications
In situ metalation of tetraphenylporphyrin (2HTPP) (sub)monolayers with Ni on a TiO2(110) surface to nickel(II)-tetraphenylporphyrin (NiTPP) depends on temperature and order of deposition, and affects conformation and bonding geometry of the porphyrin.
Published in Chemical Communications
The nanoporous AuPd (AuPdNPore) alloy catalyst showed superior chemoselectivity and high catalytic activity for the direct 1,4-hydrosilylation of the conjugated cyclic enones with hydrosilane in comparison with the monometallic nanoporous Au and Pd catalysts. The enhanced catalytic properties of AuPdNPore arise mainly from the nanoporous structure ...
Published in Chemical communications (Cambridge, England)
Two Mn(I) carbonyl complexes namely [MnBr(azpy)(CO)3] and [Mn(azpy)(CO)3(PPh3)](ClO4) (azpy = 2-phenylazopyridine) have been synthesized and characterized. Both complexes exhibit rapid CO release upon exposure to low power visible light. [MnBr(azpy)(CO)3] shows significant phototoxicity toward two malignant cell lines HeLa and MDA-MB-231.
