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Voltammetric determination of bisoprolol on a glassy carbon electrode modified by poly(arylene phthalide)

Authors
  • Zil’berg, R. A.1
  • Yarkaeva, Yu. A.1
  • Sidel’nikov, A. V.1
  • Maistrenko, V. N.1
  • Kraikin, V. A.2
  • Gileva, N. G.2
  • 1 Bashkir State University, Department of Chemistry, ul. Zaki Validi 32, Ufa, Republic of Bashkortostan, 450076, Russia , Ufa, Republic of Bashkortostan (Russia)
  • 2 Russian Academy of Sciences, Ufa Institute of Chemistry, pr. Oktyabrya 71, Ufa, Republic of Bashkortostan, 450054, Russia , Ufa, Republic of Bashkortostan (Russia)
Type
Published Article
Journal
Journal of Analytical Chemistry
Publisher
Pleiades Publishing
Publication Date
Aug 20, 2016
Volume
71
Issue
9
Pages
926–931
Identifiers
DOI: 10.1134/S1061934816090173
Source
Springer Nature
Keywords
License
Yellow

Abstract

New voltammetric sensors based on glassy carbon electrodes (GCEs) modified by poly(arylene phthalide) are studied. The electrochemical behavior of bisoprolol on GCEs modified by poly(arylene phthalide) is investigated. The effects of potential scan rate, time of accumulation on the electrode, pH of supporting electrolyte, and concentration on the current of bisoprolol electrooxidation are estimated. A procedure is developed for the voltammetric determination of bisoprolol on glassy carbon electrodes modified by poly(arylene phthalide). The dependence of the analytical signal on the concentration of bisoprolol is linear in the range 10–6–10–5 M with the limit of detection (3.4–9.8) × 10–8 M.

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