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Vapor-phase silylation for the construction of monomeric silica puncheons in the interlayer micropores of Al-MWW layered precursor.

Authors
  • Inagaki, Satoshi
  • Tatsumi, Takashi
Type
Published Article
Journal
Chemical communications (Cambridge, England)
Publication Date
May 14, 2009
Issue
18
Pages
2583–2585
Identifiers
DOI: 10.1039/b823524d
PMID: 19532897
Source
Medline
License
Unknown

Abstract

Vapor-phase silylation of Al-MWW layered precursor with SiMe(2)Cl(2) and following calcination produced an interlayer-expanded MWW structure with 12-membered ring micropores without delamination as a result of the formation of silica puncheons between the MWW sheets; strong acidity of zeolitic nature was retained.

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