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Unprecedented coexistence of cyano-bridged Mn4(III)Cr(III) and Mn2(III)Cr(III) heterobimetallic complexes in one single crystal.

Authors
  • Visinescu, Diana
  • Toma, Luminita Marilena
  • Lloret, Francesc
  • Fabelo, Oscar
  • Ruiz-Pérez, Catalina
  • Julve, Miguel
Type
Published Article
Journal
Dalton transactions (Cambridge, England : 2003)
Publication Date
Jan 07, 2009
Issue
1
Pages
37–40
Identifiers
DOI: 10.1039/b816412f
PMID: 19081969
Source
Medline
License
Unknown

Abstract

The penta-[{MnIII(4-MeO-salen)(H2O)(micro-CN)}4CrIII(CN)2]+ and trinuclear [{MnIII(4-MeO-salen)(H2O)(micro-CN)}2CrIII(CN)4](-) units coexist in 1 with weak antiferromagnetic interactions which are overcome by a dc magnetic field of 2.5 T.

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