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Two triazole-based coordination polymers: Synthesis and crystal structure characterization

Authors
  • Li, Jing
  • Ren, Hongjiang
  • Li, Jiangtao
  • Wang, Liuchang
Type
Published Article
Journal
Open Chemistry
Publisher
Walter de Gruyter GmbH
Publication Date
Feb 28, 2024
Volume
22
Issue
1
Identifiers
DOI: 10.1515/chem-2023-0211
Source
De Gruyter
Keywords
Disciplines
  • Research Article
License
Green

Abstract

Here we reported two new triazole-based coordination polymers (CPs), i.e., [Zn(Hdatrz)(μ 2-O)] n (1) together with [Mn(Hdatrz)(C2O4)] n ·n(H2O) (2) (Hdatrz = 3,5-diamino-1,2,4-triazole), which were generated under solvothermal conditions. The influence of different metal ions on the structure and properties of CPs was investigated. The CPs’ whole structures have been completely characterized by the powder X-ray diffraction, Fourier transform infrared spectroscopy, and thermogravimetric analysis. It is noteworthy that, upon excitation at 390 nm, ligands of compounds 1 and 2, as well as the metal complexes, all exhibit luminescence at 432 nm.

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