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Tuning the reactivity of Au-complexes in an Au(I)/chiral Brønsted acid cooperative catalytic system: an approach to optically active fused 1,2-dihydroisoquinolines.

Authors
  • Patil, Nitin T
  • Mutyala, Anil Kumar
  • Konala, Ashok
  • Tella, Ramesh Babu
Type
Published Article
Journal
Chemical Communications
Publisher
The Royal Society of Chemistry
Publication Date
Mar 25, 2012
Volume
48
Issue
25
Pages
3094–3096
Identifiers
DOI: 10.1039/c2cc17450b
PMID: 22344270
Source
Medline
License
Unknown

Abstract

An enantioselective cooperative catalysis protocol, utilizing achiral Au(I) complexes and chiral Brønsted acids, has been developed for the synthesis of optically pure fused 1,2-dihydroisoquinolines starting from 2-alkynylbenzaldehydes and 2-aminobenzamides.

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