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Tris(1-ethyl-3-methylimidazolium) hexachlorolanthanate.

Authors
Type
Published Article
Journal
Acta Crystallographica Section C Crystal Structure Communications
0108-2701
Publisher
International Union of Crystallography
Publication Date
Volume
58
Issue
Pt 3
Identifiers
PMID: 11870297
Source
Medline

Abstract

In the title complex, (C(6)H(11)N(2))(3)[LaCl(6)], centrosymmetric octahedral hexachlorolanthanate anions are located at the corners and face-centers of the monoclinic unit cell. The ring H atoms of the cations interact with the Cl atoms of the anions via hydrogen bonding, and bifurcation of the hydrogen bonding is observed. Cation-cation interactions via hydrogen bonding between the ring H atoms and pi-electrons of aromatic rings are also observed as in other imidazolium salts.

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