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Triamide macrocyclic chloride receptors via a one-pot tandem reduction-condensation-cyclization reaction.

Authors
  • Behera, Harekrushna1
  • Ramkumar, Venkatachalam
  • Madhavan, Nandita
  • 1 Department of Chemistry, Indian Institute of Technology, Madras, Chennai, Tamil Nadu 600036, India. [email protected] , (India)
Type
Published Article
Journal
Organic & Biomolecular Chemistry
Publisher
The Royal Society of Chemistry
Publication Date
Jun 14, 2017
Volume
15
Issue
23
Pages
4937–4940
Identifiers
DOI: 10.1039/c7ob00642j
PMID: 28485420
Source
Medline
Language
English
License
Unknown

Abstract

A pyridine containing triamide macrocycle and its substituted analog have been synthesized in one pot from the corresponding monomer without the use of coupling reagents. The macrocycle can selectively bind chloride ions. The ease of synthesis and chloride-binding properties of the macrocycle make it a highly attractive scaffold for ion-encapsulation, ion-transport and water purification.

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