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Towards Atomically Precise Supported Catalysts from Monolayer‐Protected Clusters: The Critical Role of the Support

Authors
  • Longo, Alessandro1, 2
  • de Boed, Ewoud J. J.3
  • Mammen, Nisha4
  • van der Linden, Marte3
  • Honkala, Karoliina4
  • Häkkinen, Hannu4, 4
  • de Jongh, Petra E.3
  • Donoeva, Baira3
  • 1 Ghent University, Belgium , (Belgium)
  • 2 Istituto per lo Studio dei Materiali Nanostrutturati (ISMN)-CNR, UOS Palermo, Italy , (Italy)
  • 3 Utrecht University, The Netherlands , (Netherlands)
  • 4 University of Jyväskylä, Finland , (Finland)
Type
Published Article
Journal
Chemistry - A European Journal
Publisher
Wiley (John Wiley & Sons)
Publication Date
Apr 28, 2020
Volume
26
Issue
31
Pages
7051–7058
Identifiers
DOI: 10.1002/chem.202000637
PMID: 32220016
PMCID: PMC7318640
Source
PubMed Central
Keywords
Disciplines
  • Full Papers
  • Nanomaterials | Hot Paper
License
Unknown
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Abstract

Small and shiny : X‐ray absorption spectroscopy and density functional theory computations show that the acidity of the support defines the fate of gold–phospine clusters after deposition.

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