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Thermal properties of fully delithiated olivines

Authors
  • Park, Jae-Sang
  • Oh, Seung-Min
  • Sun, Yang-Kook
  • Myung, Seung-Taek1, 2, 3, 4, 5, 6, 7
  • 1 Department of Nano Engineering
  • 2 Sejong University
  • 3 Department of Energy Engineering
  • 4 Hanyang University
  • 5 Chemistry Department
  • 6 Faculty of Science
  • 7 King Abdulaziz University
Type
Published Article
Journal
Journal of Power Sources
Publisher
Elsevier
Publication Date
Jan 01, 2014
Accepted Date
Jan 09, 2014
Volume
256
Pages
479–484
Identifiers
DOI: 10.1016/j.jpowsour.2014.01.046
Source
Elsevier
Keywords
License
Unknown

Abstract

•Carbon-coated LiMnxFe1−xPO4 (x = 0, 0.5 and 1) was fully delithiated using an oxidant NO2BF4.•Thermal properties of the Li0MnxFe1−xPO4 were studied by TG, in situ XRD, and DSC.•Phase stability of the olivines was strongly affected by Mn content in the LiMnxFe1−xPO4.•The Li0FePO4 was the most stable up to 500 °C maintaining the original olivine structure.

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