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Tetra-kis(pyridazine-κN)bis-(seleno-cyanato-κN)cobalt(II) pyridazine disolvate.

Authors
  • Wöhlert, Susanne
  • Wriedt, Mario
  • Jess, Inke
  • Näther, Christian
Type
Published Article
Journal
Acta Crystallographica Section E Structure Reports Online
Publisher
International Union of Crystallography
Publication Date
Jul 01, 2012
Volume
68
Issue
Pt 7
Identifiers
DOI: 10.1107/S1600536812027742
PMID: 22807784
Source
Medline
License
Unknown

Abstract

Reaction of cobalt(II) nitrate with potassium seleno-cyanate and pyridazine leads to single crystals of the title compound, [Co(NCSe)(2)(C(4)H(4)N(2))(4)]·2C(4)H(4)N(2), which is isotypic with its nickel(II) thio-cyanate analogue. The Co(2+) cations are coordinated by two N-bonded seleno-cyanate ligands and four N atoms from four pyridazine ligands into discrete complexes. The complexes are arranged into layers parallel to (001). These layers are separated by additional non-coordinating pyridazine ligands.

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