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Template controlled synthesis of a coordinated [11]ane-P2C NHC macrocycle.

Authors
  • Kaufhold, Oliver
  • Stasch, Andreas
  • Edwards, Peter G
  • Hahn, F Ekkehardt
Type
Published Article
Journal
Chemical communications (Cambridge, England)
Publication Date
May 14, 2007
Issue
18
Pages
1822–1824
Identifiers
PMID: 17476399
Source
Medline
License
Unknown

Abstract

Rhenium complex []Cl with the coordinated [11]ane-P(2)C(NHC) macrocycle was obtained by a metal template controlled ring formation reaction; in this reaction a coordinated NH,NH-stabilised imidazolidin-2-ylidene ligand was connected via the nitrogen atoms to two phenyl substituents of a 2-fluorophenyl substituted diphosphine ligand.

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