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[TcCl4(H2O)2] and [Cl3(H2O)2TcOTc(H2O)2Cl3]--two molecular intermediates of the hydrolysis of technetium(IV).

Authors
  • Yegen, Eda
  • Hagenbach, Adelheid
  • Abram, Ulrich
Type
Published Article
Journal
Chemical communications (Cambridge, England)
Publication Date
Nov 28, 2005
Issue
44
Pages
5575–5577
Identifiers
PMID: 16358068
Source
Medline
License
Unknown

Abstract

Two molecular intermediates of the hydrolysis of technetium tetrachloride, cis-[TcCl4(H2O)2] and [Cl3(H2O)2TcOTc(H2O)2Cl3], were isolated and structurally characterised, suggesting that the hydrolytic degradation of technetium(IV) compounds occurs stepwise with the polymeric 'TcO2...nH2O' as a less defined final product.

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