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Synthesis of symmetrical and unsymmetrical 9,10-diarylanthracene derivatives via bis-Suzuki-Miyaura cross-coupling reaction

Authors
  • KOTHA, S
  • GHOSH, AK
  • DEODHAR, KD
Publication Date
Jan 01, 2004
Identifiers
DOI: 10.1055/s-2004-815981
OAI: oai:dsapce.library.iitb.ac.in:10054/7916
Source
DSpace at IIT Bombay
Keywords
Language
English
License
Unknown
External links

Abstract

Synthesis of various 9, 10-diarylanthracene derivatives via bis-Suzuki-Miyaura cross-coupling reaction as a key step is described. Availability of the 9,10-dithienylanthracenes derivatives where the thiophene unit is present in the molecule (e. g. 11, 12, 14) may provide an easy access to novel polymer and/or dendrimer preparation. In addition, we have synthesized unsymmetrical 9,10-diarylanthracene derivatives 20-25 by the Suzuki-Miyaura cross-coupling reaction, which are difficult to prepare by other transition metal-catalyzed cross-coupling reactions.

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