Synthesis, structure and magnetism of a novel carboxylate bridged manganese(II) sheet structure containing the first unsupported aqua bridge.
- Published Article
Dalton transactions (Cambridge, England : 2003)
- Publication Date
Sep 21, 2004
The structural characterisation of a 2D sheet complex [[Mn2(Hetheidi)2(mu-H2O)(H2O)].3H2O]n 1 [Hetheidi =DL-N-(1-hydroxymethylpropyl)iminodiacetic acid] assembled from the tetradentate ligand Hetheidi and MnCl2 reveals the presence of rare unsupported mu-aqua bridges and novel hydrogen-bonded water channels, which bind the sheets together.
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The corresponding record at NLM can be accessed at https://www.ncbi.nlm.nih.gov/pubmed/15349154