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Synthesis, structure and magnetism of a novel carboxylate bridged manganese(II) sheet structure containing the first unsupported aqua bridge.

Authors
  • Goodwin, Jeremy C
  • Price, Daniel J
  • Heath, Sarah L
Type
Published Article
Journal
Dalton transactions (Cambridge, England : 2003)
Publication Date
Sep 21, 2004
Issue
18
Pages
2833–2835
Identifiers
PMID: 15349154
Source
Medline
License
Unknown

Abstract

The structural characterisation of a 2D sheet complex [[Mn2(Hetheidi)2(mu-H2O)(H2O)].3H2O]n 1 [Hetheidi =DL-N-(1-hydroxymethylpropyl)iminodiacetic acid] assembled from the tetradentate ligand Hetheidi and MnCl2 reveals the presence of rare unsupported mu-aqua bridges and novel hydrogen-bonded water channels, which bind the sheets together.

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