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Synthesis of odd generation triazine dendrimers using a divergent, macromonomer approach.

Authors
  • Lim, Jongdoo
  • Mintzer, Meredith A
  • Perez, Lisa M
  • Simanek, Eric E
Type
Published Article
Journal
Organic Letters
Publisher
American Chemical Society
Publication Date
Mar 19, 2010
Volume
12
Issue
6
Pages
1148–1151
Identifiers
DOI: 10.1021/ol902669g
PMID: 20170155
Source
Medline
License
Unknown

Abstract

Using a macromonomer, first, third, and fifth generation triazine dendrimers can be prepared using a divergent approach. The nine-step process to the fifth generation target relies on an iterative two-reactions-per-generation strategy to yield the desired material in approximately 48% overall yield. This target displays 96 surface groups. NMR spectroscopy and mass spectrometry show that exceptionally narrow polydispersity is achieved using this strategy.

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