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Synthesis, isolation and characterization of cationic gold(I) N-heterocyclic carbene (NHC) complexes

Authors
  • de Fremont, P
  • Stevens, ED
  • Fructos, MR
  • Diaz-Requejo, MM
  • Perez, PJ
  • Nolan, Steven
Publication Date
Jan 01, 2006
Source
Ghent University Institutional Archive
Keywords
Language
English
License
Unknown
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Abstract

A number of cationic gold(I) complexes have been synthesized and found to be stabilized by the use of N-heterocyclic carbene ligands. These species are often employed as in situ-generated reactive intermediates in gold catalyzed organic transformations. An isolated, well-defined species was tested in gold-mediated carbene transfer reactions from ethyl diazoacetate.

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