Synthesis of galactomannan fragments to help NMR assignment of polysaccharides extracted from lichens.
-
Authors
-
-
David, Louis-Philippe1
-
Ferron, Solenn2
-
Favreau, Bénédicte1
-
Yeni, Oznur3
-
Ollivier, Simon4, 5
-
Ropartz, David4, 5
-
Compagnon, Isabelle3
-
Ferrières, Vincent1
-
Le Dévéhat, Françoise2
-
Legentil, Laurent1
-
1
Univ Rennes, Ecole Nationale Supérieure de Chimie de Rennes, CNRS, ISCR - UMR 6226, F-35000 Rennes, France. [email protected].
,
(France)
-
2
Univ Rennes, CNRS, ISCR - UMR 6226, F-35000 Rennes, France.
,
(France)
-
3
Univ Lyon, Université Claude Bernard Lyon 1, CNRS, Institut Lumière Matière, F-69622 Villeurbanne, France.
,
(France)
-
4
INRAE, UR BIA, F-44316 Nantes, France.
,
(France)
-
5
INRAE, BIBS Facility, F-44316 Nantes, France.
,
(France)
- Type
- Published Article
- Journal
-
Organic & Biomolecular Chemistry
- Publisher
-
The Royal Society of Chemistry
- Publication Date
-
Mar 20, 2024
- Volume
-
22
- Issue
-
12
- Pages
-
2395–2403
- Identifiers
-
DOI: 10.1039/d4ob00047a
-
PMID: 38412026
- Source
-
Medline
- Language
-
English
- License
-
Unknown
Abstract
The synthesis of six model trisaccharides representative of galactomannans produced by lichens was performed through stereoselective glycosylation. These standards include linear and branched galactomannans bearing either galactofuranosyl or galactopyranosyl entities. The complete assignment of 1H and 13C signals for both forms of synthetically reduced oligosaccharides was performed. The resulting NMR data were used to quickly demonstrate the structural characteristics of minor polysaccharides within different extracts of three representative lichens.
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine.
This record was last updated on 03/24/2024 and may not reflect the most current and accurate biomedical/scientific data available from NLM.
The corresponding record at NLM can be accessed at
https://www.ncbi.nlm.nih.gov/pubmed/38412026
