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Synthesis, characterisation, and oxygen atom transfer reactions involving the first gold(I)-alkylperoxo complexes.

Authors
  • Collado, Alba
  • Gómez-Suárez, Adrián
  • Oonishi, Yoshihiro
  • Slawin, Alexandra M Z
  • Nolan, Steven P
Type
Published Article
Journal
Chemical Communications
Publisher
Royal Society of Chemistry (RSC)
Publication Date
Nov 25, 2013
Volume
49
Issue
91
Pages
10745–10747
Identifiers
DOI: 10.1039/c3cc47030j
PMID: 24107923
Source
Medline
License
Unknown

Abstract

The synthesis of a new class of organogold species containing a peroxo moiety is reported. Complexes [Au(IPr)(OO(t)Bu)] and [Au(SIPr)(OO(t)Bu)] have been synthesised via a straightforward methodology using the parent gold(I) hydroxide complexes as synthons. These complexes have been successfully used in oxygen-transfer reactions to triphenylphosphine.

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