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Synthesis of Biaryls via Ligand-Free Suzuki-Miyaura Cross-Coupling Reactions: A Review of Homogeneous and Heterogeneous Catalytic Developments

Authors
Type
Published Article
Journal
Advanced Synthesis & Catalysis
Publisher
Wiley
Publication Date
Sep 10, 2016
Volume
358
Issue
21
Pages
3320–3349
Identifiers
DOI: 10.1002/adsc.201600354
Source
MyScienceWork
Keywords
License
White

Abstract

This review describes the recent developments in the field of Suzuki-Miyaura cross-coupling reaction, in particular with regard to ligand-free catalysis. The catalysts outlined here allow convenient and green synthetic pathways specifically for the construction of C-C bonds. They enable the synthesis of biaryls by the coupling arylboronic acids with aryl halides. The literature reporting ligand-free synthesis of biaryls from 2010 to May 2015 has been reviewed.

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