Affordable Access

Publisher Website

The synergistic effect of nanoporous AuPd alloy catalysts on highly chemoselective 1,4-hydrosilylation of conjugated cyclic enones.

Authors
  • Chen, Qiang
  • Tanaka, Shinya
  • Fujita, Takeshi
  • Chen, Luyang
  • Taketoshi Minato
  • Ishikawa, Yoshifumi
  • Chen, Mingwei
  • Asao, Naoki
  • Yamamoto, Yoshinori
  • Jin, Tienan
Type
Published Article
Journal
Chemical Communications
Publisher
The Royal Society of Chemistry
Publication Date
Mar 28, 2014
Volume
50
Issue
25
Pages
3344–3346
Identifiers
DOI: 10.1039/c3cc49524h
PMID: 24535201
Source
Medline
License
Unknown

Abstract

The nanoporous AuPd (AuPdNPore) alloy catalyst showed superior chemoselectivity and high catalytic activity for the direct 1,4-hydrosilylation of the conjugated cyclic enones with hydrosilane in comparison with the monometallic nanoporous Au and Pd catalysts. The enhanced catalytic properties of AuPdNPore arise mainly from the nanoporous structure and the synergistic effect of the AuPd alloy.

Report this publication

Statistics

Seen <100 times