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Structure of PbBi2Nb2O9 and its Cr-doped layered perovskite system and their photocatalytic activities

  • Hong, SJ
  • Borse, PH
  • Ji, SM
  • Jang, JS
  • Lee, JS
  • Jeong, ED
  • Kim, HG
Publication Date
Jul 01, 2007
[email protected]
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In the search for efficient photocatalysts for water splitting under visible light, the effect of chromium doping in a (100) layered Aurivillius-phase perovskite material, PbBi2Nb2O9, has been studied. The Cr-doped PbBi2Nb2O9 showed three absorption edges: the main edge due to the oxide at 431 nm and shoulders due to the chromium ions at 470 nm and 600 nm, respectively. The Pt/Gr-doped PbBi2Nb2O9 photocatalyst was more active than the undoped PbBi2Nb2O9 for photocatalytic decomposition of water-methanol solution. This is attributed to Cr+ ions having an important role in increasing QYs in the PbBi2Nb2O9. / X / 1 / 1 / 12 / scie / scopus / kci

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