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Structural influence of chiral tertiary aminonaphthol ligands on the asymmetric phenyl transfer to aromatic aldehydes.

Authors
  • Wei, Hui
  • Yin, Lu
  • Luo, Haibin
  • Li, Xingshu
  • Chan, Albert S C
Type
Published Article
Journal
Chirality
Publisher
Wiley (John Wiley & Sons)
Publication Date
Mar 01, 2011
Volume
23
Issue
3
Pages
222–227
Identifiers
DOI: 10.1002/chir.20903
PMID: 20882598
Source
Medline
License
Unknown

Abstract

A series of chiral tertiary aminonaphthol ligands were prepared from 2-naphthol, (S)-1-phenylethylamine, and aldehydes with diverse substituted groups. The results of asymmetric phenyl transfer to aromatic aldehydes catalyzed by these chiral ligands indicated that enantioselectivities were greatly influenced by the electronic and steric effects of the ligands.

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