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Stability of Pt(II)-based H2-evolving catalysts against H2 in aqueous solution.

Authors
  • Yamauchi, Kosei
  • Masaoka, Shigeyuki
  • Sakai, Ken
Type
Published Article
Journal
Dalton Transactions
Publisher
The Royal Society of Chemistry
Publication Date
Dec 14, 2011
Volume
40
Issue
46
Pages
12447–12449
Identifiers
DOI: 10.1039/c1dt11217a
PMID: 22015472
Source
Medline
License
Unknown

Abstract

To answer the question of whether Pt(II)-based H(2)-evolving catalysts are stable upon exposure to H(2), the behaviours of some platinum(II) complexes in the presence of H(2) (5 × 10(-4) - 1 atm) have been followed spectrophotometrically. The results reveal that some catalysts are highly stable upon exposure to H(2).

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