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Soft X-ray Absorption Spectroscopy Study of Spin Crossover Fe-Compounds: Persistent High Spin Configurations under Soft X-ray Irradiation

Authors
  • Mohamed, Ahmed Yousef
  • Lee, Minji
  • Kitase, Kosuke
  • Kitazawa, Takafumi
  • Kim, Jae-Young
  • Cho, Deok-Yong
Publication Date
Nov 19, 2018
Source
MDPI
Keywords
Language
English
License
Green
External links

Abstract

170 K), manifesting HS trapping due to the X-ray irradiation. This is in strong contrast to the normal SCO behavior observed in FeII(1,10-phenanthroline)2(NCS)2, implying that the structure of the ligand chains in the polymers with relatively loose Fe-N coordination might allow a structural adaptation to stabilize the metastable HS state under the soft X-ray irradiation.

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