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Skeletal recombination reaction of N-fused pentaphyrin(1.1.1.1.1) via bromination.

Authors
  • Suzuki, Masaaki
  • Hoshino, Tyuji
  • Neya, Saburo
Type
Published Article
Journal
Organic Letters
Publisher
American Chemical Society
Publication Date
Jan 17, 2014
Volume
16
Issue
2
Pages
327–329
Identifiers
DOI: 10.1021/ol403242z
PMID: 24344777
Source
Medline
License
Unknown

Abstract

N-Fused [22]pentaphyrin(1.1.1.1.1) transformed into recombined N-fused pentaphyrin bromide after treatment with N-bromosuccinimide. This bromide was highly reactive to nucleophiles to give the corresponding substituted products including aminated, oxidized, and unsubstituted derivatives.

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