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In situ x-ray photoelectron spectroscopy of model catalysts: at the edge of the gap.

Authors
  • Blomberg, S
  • Hoffmann, M J
  • Gustafson, J
  • Martin, N M
  • Fernandes, V R
  • Borg, A
  • Liu, Z
  • Chang, R
  • Matera, S
  • Reuter, K
  • Lundgren, E
Type
Published Article
Journal
Physical Review Letters
Publisher
American Physical Society
Publication Date
Mar 15, 2013
Volume
110
Issue
11
Pages
117601–117601
Identifiers
PMID: 25166577
Source
Medline
License
Unknown

Abstract

We present high-pressure x-ray photoelectron spectroscopy (HP-XPS) and first-principles kinetic Monte Carlo study addressing the nature of the active surface in CO oxidation over Pd(100). Simultaneously measuring the chemical composition at the surface and in the near-surface gas phase, we reveal both O-covered pristine Pd(100) and a surface oxide as stable, highly active phases in the near-ambient regime accessible to HP-XPS. Surprisingly, no adsorbed CO can be detected during high CO(2) production rates, which can be explained by a combination of a remarkably short residence time of the CO molecule on the surface and mass-transfer limitations in the present setup.

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