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Silylstannations of alpha,beta-unsaturated carbonyl compounds via the generation of Bu3Sn- in ionic liquids.

Authors
  • Dickson, Steven
  • Dean, Darrell
  • Singer, Robert D
Type
Published Article
Journal
Chemical communications (Cambridge, England)
Publication Date
Sep 21, 2005
Issue
35
Pages
4474–4476
Identifiers
PMID: 16136255
Source
Medline
License
Unknown

Abstract

The tributylstannyl anion, Bu3Sn-, can be generated in imidazolium based ionic liquids from Me3SiSnBu3 and reacted with alpha,beta-unsaturated carbonyl compounds to afford 3-tributylstannylated products in good yields.

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