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Selective Cascade Reaction of Bisallenes via Palladium-Catalyzed Aerobic Oxidative Carbocyclization-Borylation and Aldehyde Trapping

Authors
  • Naidu, Veluru Ramesh
  • Posevins, Daniels
  • Volla, Chandra M. R.
  • Bäckvall, Jan-Erling
Publication Date
Jan 01, 2017
Identifiers
DOI: 10.1002/anie.201610524
OAI: oai:DiVA.org:su-141360
Source
DiVA - Academic Archive On-line
Keywords
Language
English
License
Green
External links

Abstract

A cascade reaction, consisting of a palladium-catalyzed regioselective aerobic oxidative carbocyclization-borylation of bisallenes and a final aldehyde trapping, afforded triene alcohols with high diastereoselectivity. The cascade reaction occurs under mild reaction conditions and proceeds via an allylboron intermediate that is trapped by the aldehyde in a stereoselective manner.

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