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Ring cleavage and successive aldol reaction of 3-[(trialkylsilyl)methyl]cyclobutanones.

Authors
  • Matsuo, Jun-ichi
  • Harada, Kosuke
  • Kawano, Mizuki
  • Okuno, Ryosuke
  • Ishibashi, Hiroyuki
Type
Published Article
Journal
Organic Letters
Publisher
American Chemical Society
Publication Date
Nov 18, 2011
Volume
13
Issue
22
Pages
5986–5989
Identifiers
DOI: 10.1021/ol202424p
PMID: 22007918
Source
Medline
License
Unknown

Abstract

3-[(Trialkylsilyl)methyl]cyclobutanones reacted with aldehydes by activation with titanium(IV) chloride to give acyclic β,γ-unsaturated β'-hydroxyketones.

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