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Rh(III)-Catalyzed Oxidative Coupling of Benzoic Acids with Geminal-Substituted Vinyl Acetates: Synthesis of 3-Substituted Isocoumarins.

Authors
  • Zhang, Mingliang
  • Zhang, Hui-Jun
  • Han, Tiantian
  • Ruan, Wenqing
  • Wen, Ting-Bin
Type
Published Article
Journal
The Journal of Organic Chemistry
Publisher
American Chemical Society
Publication Date
Jan 02, 2015
Volume
80
Issue
1
Pages
620–627
Identifiers
DOI: 10.1021/jo502231y
PMID: 25436434
Source
Medline
License
Unknown

Abstract

The Rh(III)-catalyzed C-H activation initiated cyclization of benzoic acids with electron-rich geminal-substituted vinyl acetates was described. The reaction was employed to prepare a range of 3-aryl and 3-alkyl substituted isocoumarins selectively.

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