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Recent Progress on Metal–Organic Framework and Its Derivatives as Novel Fire Retardants to Polymeric Materials

Authors
  • Zhang, Jing1, 2
  • Li, Zhi3
  • Qi, Xiao-Lin1
  • Wang, De-Yi1
  • 1 IMDEA Materials Institute, C/Eric Kandel 2, Getafe, Madrid, 28906, Spain , Getafe (Spain)
  • 2 Universidad Politécnica de Madrid, E.T.S. de Ingenieros de Caminos, Madrid, 28040, Spain , Madrid (Spain)
  • 3 Chongqing Jiaotong University, Chongqing, 400074, People’s Republic of China , Chongqing (China)
Type
Published Article
Journal
Nano-Micro Letters
Publisher
Springer Singapore
Publication Date
Aug 25, 2020
Volume
12
Issue
1
Identifiers
DOI: 10.1007/s40820-020-00497-z
Source
Springer Nature
Keywords
License
Green

Abstract

High flammability of polymers has become a major issue which has restricted its applications. Recently, highly crystalline materials and metal–organic frameworks (MOFs), which consisted of metal ions and organic linkers, have been intensively employed as novel fire retardants (FRs) for a variety of polymers (MOF/polymer). The MOFs possessed abundant transition metal species, fire-retardant elements and potential carbon source accompanied with the facile tuning of the structure and property, making MOF, its derivatives and MOF hybrids promising for fire retardancy research. The recent progress and strategies to prepare MOF-based FRs are emphasized and summarized. The fire retardancy mechanisms of MOF/polymer composites are explained, which may guide the future design for efficient MOF-based FRs. Finally, the challenges and prospects related to different MOF-based FRs are also discussed and aim to provide a fast and holistic overview, which is beneficial for researchers to quickly get up to speed with the latest development in this field.

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