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Recent development in in situ NMR study on heterogeneous catalysis: mechanisms of light alkane functionalisation.

Authors
Type
Published Article
Journal
Chemical Communications
1364-548X
Publisher
The Royal Society of Chemistry
Publication Date
Volume
48
Issue
18
Pages
2370–2384
Identifiers
DOI: 10.1039/c2cc16882k
PMID: 22252405
Source
Medline

Abstract

In situ NMR studies of C(1)-C(5) light alkane activation and functionalisation in heterogeneous catalytic systems are overviewed. The results obtained from the NMR technique, particularly those quantitative ones, provide unique information on the activation of alkane molecules and the nature of relevant intermediates, leading to better understanding reaction mechanisms and designing catalysts.

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