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Recent achievements in copper catalysis for C–N bond formation

Authors
  • Averin, Alexei D.1
  • Abel, Anton S.1
  • Grigorova, Olga K.1
  • Latyshev, Gennadij V.1
  • Kotovshchikov, Yury N.1
  • Mitrofanov, Alexander Yu.1
  • Bessmertnykh-Lemeune, Alla2
  • Beletskaya, Irina P.3
  • 1 Chemistry, Russian Federation , (Russia)
  • 2 Laboratoire de Chimie, France , (France)
  • 3 Chemistry, Leninskie Gory, 1-3, 119991 , (Russia)
Type
Published Article
Journal
Pure and Applied Chemistry
Publisher
Walter de Gruyter GmbH
Publication Date
Jun 25, 2020
Volume
92
Issue
8
Pages
1181–1199
Identifiers
DOI: 10.1515/pac-2020-0301
Source
De Gruyter
Keywords
License
Yellow

Abstract

A mini-review describes the development of the catalysis by Cu(I) complexes aimed at the formation of C–N bond at the Lomonosov MSU during 2010s. The main approach employs the amination of aryl and heteroaryl halides with the amines and polyamines, in this direction a great versatility of starting compounds was achieved: adamantane-containing amines, linear diamines, oxadiamines and polyamines, various aryl iodides and bromides, derivatives of pyridine, and quinoline were used for this purpose. In more peculiar cases, the copper catalysis was used for steroids transformations, including vinylation of azoles, wide-spread “click” reactions for the conjugate syntheses, and successful heterogenezation of the copper catalysts were also undertaken.

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