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Reactions of osmabenzene with silver/copper acetylides: from metallabenzene to benzene.

Authors
  • Han, Feifei
  • Li, Jinhua
  • Zhang, Hong
  • Wang, Tongdao
  • Lin, Zhenyang
  • Xia, Haiping
Type
Published Article
Journal
Chemistry - A European Journal
Publisher
Wiley (John Wiley & Sons)
Publication Date
Jan 07, 2015
Volume
21
Issue
2
Pages
565–567
Identifiers
DOI: 10.1002/chem.201405220
PMID: 25412982
Source
Medline
Keywords
License
Unknown

Abstract

The transformations of metallabenzene to substituted benzenes have been achieved by reactions of osmabenzenes with silver/copper acetylides. In this investigation, novel tetraphenylphosphonium salts containing two phosphonium substituents on the same benzene ring are generated.

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