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Rapid carbonylative coupling reactions using palladium(I) dimers: applications to 11CO-radiolabelling for the synthesis of PET tracers.

Authors
  • Buscemi, Gabriella
  • Miller, Philip W
  • Kealey, Steven
  • Gee, Antony D
  • Long, Nicholas J
  • Passchier, Jan
  • Vilar, Ramon
Type
Published Article
Journal
Organic & Biomolecular Chemistry
Publisher
The Royal Society of Chemistry
Publication Date
May 07, 2011
Volume
9
Issue
9
Pages
3499–3503
Identifiers
DOI: 10.1039/c1ob05268c
PMID: 21431235
Source
Medline
License
Unknown

Abstract

Palladium dimers with sterically hindered phosphines have been shown to be excellent pre-catalysts for the aminocarbonylation of aryl halides to yield amides and one of them has been successfully employed as a pre-catalyst for the synthesis of (11)C-radiolabelled amides for PET imaging.

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