Radical-Induced 1,2-Migrations of Boron Ate Complexes.
Organisch-Chemisches Institut Westfälische Wilhelms-Universität Corrensstrasse 40 48149 Münster Germany.
- Published Article
Advanced Synthesis & Catalysis
- Publication Date
May 26, 2020
1,2-Boron ate rearrangements represent a fundamental class of transformations to establish new C-C bonds while retaining the valuable boron moiety in the product. In established ionic processes, the boron ate complex is activated by an external electrophile to induce a 1,2-migration from boron to an adjacent sp 3 or sp 2 carbon atom. Recently, two complementary radical polar crossover approaches have been explored for both classes, 1,2-migrations to sp 2 and sp 3 carbon centers. This review describes the general concepts in this emerging research field and summarizes recent developments of radical-induced 1,2-migrations from boron to carbon. © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.
Report this publication
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine.
This record was last updated on 10/06/2020 and may not reflect the most current and accurate biomedical/scientific data available from NLM.
The corresponding record at NLM can be accessed at https://www.ncbi.nlm.nih.gov/pubmed/32612487