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Radical-Induced 1,2-Migrations of Boron Ate Complexes.

Authors
  • Kischkewitz, Marvin1
  • Friese, Florian W1
  • Studer, Armido1
  • 1 Organisch-Chemisches Institut Westfälische Wilhelms-Universität Corrensstrasse 40 48149 Münster Germany. , (Germany)
Type
Published Article
Journal
Advanced Synthesis & Catalysis
Publisher
Wiley
Publication Date
May 26, 2020
Volume
362
Issue
11
Pages
2077–2087
Identifiers
DOI: 10.1002/adsc.201901503
PMID: 32612487
Source
Medline
Keywords
Language
English
License
Unknown

Abstract

1,2-Boron ate rearrangements represent a fundamental class of transformations to establish new C-C bonds while retaining the valuable boron moiety in the product. In established ionic processes, the boron ate complex is activated by an external electrophile to induce a 1,2-migration from boron to an adjacent sp 3 or sp 2 carbon atom. Recently, two complementary radical polar crossover approaches have been explored for both classes, 1,2-migrations to sp 2 and sp 3 carbon centers. This review describes the general concepts in this emerging research field and summarizes recent developments of radical-induced 1,2-migrations from boron to carbon. © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.

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