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Radiation-Induced Reaction of Carbon Dioxide with Ethylene.

Authors
Type
Published Article
Journal
Science
0036-8075
Publisher
American Association for the Advancement of Science (AAAS)
Publication Date
Volume
134
Issue
3482
Pages
839–840
Identifiers
PMID: 17817397
Source
Medline

Abstract

The gamma irradiation of mixtures of carbon dioxide with ethylene yielded long-chain carboxylic acids. The G(-ethylene) values varied with reaction temperature from essentially zero at -78 degrees C to 175 at 100 degrees C. Under the same conditions, the substitution of free radical agents for radiation gave polyethylene.

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