The structures of novel macrolide antibiotics, quinolidomicins A1, A2 and B1, were elucidated as shown in Fig. 1 by NMR spectral analysis including a variety of two-dimensional techniques. The quinolidomicins possess a novel 60-membered macrolide ring, which is to our knowledge the largest among natural products.
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The corresponding record at NLM can be accessed at https://www.ncbi.nlm.nih.gov/pubmed/8244884