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PVT properties of UNEX/HCCD-PEG diluent phenyl trifluoromethyl sulfone (FS-13) and experimental measurement of vapour pressure in 283.15–363.15 K range

Authors
  • Kumar, Shekhar1
  • Muthukumar, M.1
  • Sinha, P. K.1
  • Kamachi Mudali, U.1
  • Natarajan, R.1
  • 1 Indira Gandhi Centre for Atomic Research, Reprocessing Group, Kalpakkam, 603102, India , Kalpakkam (India)
Type
Published Article
Journal
Journal of Radioanalytical and Nuclear Chemistry
Publisher
Springer Netherlands
Publication Date
Apr 09, 2011
Volume
289
Issue
1
Pages
247–249
Identifiers
DOI: 10.1007/s10967-011-1070-6
Source
Springer Nature
Keywords
License
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Abstract

Phenyl trifluoromethyl sulfone (FS-13) is a polar diluent, proposed in literature as an alternate to nitrobenzene, in UNEX/HCCD-PEG processes for better physical properties. Its PVT properties and accurate expression for estimation of its vapour pressure are not available in the literature. Recently PVT properties of FS-13 were estimated by authors and its vapour pressure was experimentally measured at temperatures ranging from 263.15 to 363.15 K. In this paper, results of these studies are presented.

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