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Pseudopeptidic ligands: exploring the self-assembly of isophthaloylbisglycine (H2IBG) and divalent metal ions.

Authors
  • Dokorou, Vassiliki N
  • Milios, Constantinos J
  • Tsipis, Athanassios C
  • Haukka, Matti
  • Weidler, Peter G
  • Powell, Annie K
  • Kostakis, George E
Type
Published Article
Journal
Dalton Transactions
Publisher
The Royal Society of Chemistry
Publication Date
Oct 28, 2012
Volume
41
Issue
40
Pages
12501–12513
Identifiers
PMID: 22955234
Source
Medline
License
Unknown

Abstract

We present a systematic study of the complexation of the new pseudopeptidic ligand isophthaloylbisglycine (H(2)IBG) with divalent metal ions of varying ionic radius. This work represents the initial employment of H(2)IBG in the coordination chemistry of alkaline earth, 3d transition, Zn(II) and Cd(II) metal elements. Infrared, NMR, thermal, magnetic, adsorption and theoretical studies of these compounds are also discussed.

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