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Pseudobinuclear, [Bi(S2CNiPr2)3]2, and Pseudopolymeric, [Bi(S2CNiPr2)2][Bi(S2CNiPr2)Cl3], Bismuth(III) Complexes: Synthesis, Supramolecular Self-Assembly (the Role of Secondary Bi⋅⋅⋅S, Bi⋅⋅⋅Cl, and S⋅⋅⋅Cl Interactions), and Thermal Behavior

Authors
  • Novikova, E. V.1
  • Zaeva, A. S.1
  • Denisov, G. L.2
  • Egorova, I. V.3
  • Ivanov, A. V.1
  • 1 Institute of Geology and Nature Management, Far Eastern Branch, Russian Academy of Sciences, Blagoveshchensk, 675000, Russia , Blagoveshchensk (Russia)
  • 2 Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 119991, Russia , Moscow (Russia)
  • 3 Blagoveshchensk State Pedagogical University, Blagoveshchensk, 675000, Russia , Blagoveshchensk (Russia)
Type
Published Article
Journal
Russian Journal of Inorganic Chemistry
Publisher
Pleiades Publishing
Publication Date
Jan 01, 2022
Volume
67
Issue
1
Pages
91–104
Identifiers
DOI: 10.1134/S0036023622010077
Source
Springer Nature
Keywords
Disciplines
  • Coordination Compounds
License
Yellow

Abstract

AbstractPseudobinuclear, [Bi(S2CNiPr2)3]2 (I), and 1D pseudopolymeric, [Bi(S2CNiPr2)2][Bi(S2CNiPr2)Cl3] (II), bismuth(III) complexes have been synthesized and structurally characterized. Secondary Bi⋅⋅⋅S, Bi⋅⋅⋅Cl, and S⋅⋅⋅Cl bonds combine mononuclear structural units of the complexes, playing a key role in self-assembly of their supramolecular structures. The thermal behavior of the compounds has been studied by simultaneous thermal analysis under an argon atmosphere. It has been determined by energy dispersive X-ray microanalysis and scanning electron microscopy that the residual substances after thermolysis of I/II are microcrystalline Bi2S3/Bi2S3, BiCl3.

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