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Probing the substrate specificity of the catalytically self-sufficient cytochrome P450 RhF from a Rhodococcus sp.

Authors
  • Celik, Ayhan
  • Roberts, Gareth A
  • White, John H
  • Chapman, Stephen K
  • Turner, Nicholas J
  • Flitsch, Sabine L
Type
Published Article
Journal
Chemical communications (Cambridge, England)
Publication Date
Nov 21, 2006
Issue
43
Pages
4492–4494
Identifiers
PMID: 17283795
Source
Medline
License
Unknown

Abstract

Analysis of the substrate specificity of the self-sufficient cytochrome P450 RhF revealed that the enzyme tends to catalyse the dealkylation of substituted alkyl-aryl ethers with shorter alkyl moieties more readily than equivalent compounds with longer alkyl groups.

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