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Preparation and characterisation of heterobimetallic copper-tungsten hydride complexes.

Authors
  • Hicken, Alexandra1
  • White, Andrew J P2
  • Crimmin, Mark R2
  • 1 SSCP DTP, Grantham Institute, Imperial College London, South Kensington, London, SW7 2AZ, UK and Department of Chemistry, Imperial College London, South Kensington, London, SW7 2AZ, UK. [email protected]
  • 2 Department of Chemistry, Imperial College London, South Kensington, London, SW7 2AZ, UK. [email protected]
Type
Published Article
Journal
Dalton Transactions
Publisher
The Royal Society of Chemistry
Publication Date
Aug 21, 2018
Volume
47
Issue
31
Pages
10595–10600
Identifiers
DOI: 10.1039/c8dt01569d
PMID: 29786734
Source
Medline
Language
English
License
Unknown

Abstract

The preparation and structural characterisation of three new heterobimetallic hydride complexes containing 3-centre,2-electron W-H-Cu bonds is reported. These complexes have been characterised by single crystal X-ray crystallography and multinuclear NMR spectroscopy. The bonding in these complexes has been analysed by DFT calculations.

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