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Postsynthesis transformation of three-dimensional framework into a lamellar zeolite with modifiable architecture.

Authors
  • Roth, Wieslaw J
  • Shvets, Oleksiy V
  • Shamzhy, Mariya
  • Chlubná, Pavla
  • Kubů, Martin
  • Nachtigall, Petr
  • Čejka, Jiří
Type
Published Article
Journal
Journal of the American Chemical Society
Publisher
American Chemical Society
Publication Date
Apr 27, 2011
Volume
133
Issue
16
Pages
6130–6133
Identifiers
DOI: 10.1021/ja200741r
PMID: 21456511
Source
Medline
License
Unknown

Abstract

Mild treatment of zeolite UTL results in degradation of its structure with preservation of the initially present dense layers connected by D4R "bridges". The lamellar product obtained through this 3D to 2D zeolite conversion has been structurally modified similar to methodologies applied to layered zeolite precursors, which show the opposite 2D to 3D zeolite transformation.

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