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[email protected] Hybrids: Synthesis and Applications

Authors
  • sun, jiamin
  • abednatanzi, sara
  • van der voort, pascal
  • liu, ying-ya
  • leus, karen
Publication Date
May 21, 2020
Identifiers
DOI: 10.3390/catal10050578
OAI: oai:mdpi.com:/2073-4344/10/5/578/
Source
MDPI
Keywords
Language
English
License
Green
External links

Abstract

The hybrid materials that are created by supporting or incorporating polyoxometalates (POMs) into/onto metal&ndash / organic frameworks (MOFs) have a unique set of properties. They combine the strong acidity, oxygen-rich surface, and redox capability of POMs, while overcoming their drawbacks, such as difficult handling, a low surface area, and a high solubility. MOFs are ideal hosts because of their high surface area, long-range ordered structure, and high tunability in terms of the pore size and channels. In some cases, MOFs add an extra dimension to the functionality of hybrids. This review summarizes the recent developments in the field of [email protected] hybrids. The most common applied synthesis strategies are discussed, together with major applications, such as their use in catalysis (organocatalysis, electrocatalysis, and photocatalysis). The more than 100 papers on this topic have been systematically summarized in a handy table, which covers almost all of the work conducted in this field up to now.

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